Trimethylamine → N-Octylisostearamide

HRID 1284414

반응식

HRID 1284414 반응식
[C:1](Cl)(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH:16]([CH3:18])[CH3:17].C(O)(=O)CCCCCCCCCCCCCCC(C)C.S(Cl)(Cl)=O.[CH2:45]([NH2:53])[CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52].CN(C)C>CCOCC.CN(C)C=O>[CH2:45]([NH:53][C:1](=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH:16]([CH3:18])[CH3:17])[CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52]

참가 물질

8

반응물 5

HCID 1146TrimethylamineHCID 8143OctylamineHCID 2185916-Methylheptadecanoic AcidHCID 24386Thionyl ChlorideHCID 118402Heptadecanoyl chloride, 16-methyl-

생성물 1

HCID 20150929N-Octylisostearamide

시약·촉매·용매 2

HCID 3283Diethyl Ether용매HCID 6228Dimethylformamide용매

실험 절차

Isostearoyl chloride, prepared from 20 g isostearic acid, 10.1 g thionyl chloride and 0.2 ml dimethyl formamide, according to the procedure of Example 1, is added to 11 g (0.09 mole) n-octylamine and 10 g (0.10 mole) trimethylamine in 100 ml ether. The reaction mixture is treated in accordance with the procedure of Example 2, yielding 22 g of an amber oil, which exhibits infrared spectra values typical of a secondary amide.

후처리

  1. additionThe reaction mixture is treated in accordance with the procedure of Example 2

출처 및 근거

ORD 기록
ord-3a39ca19a7214b18927cf17f5e1fbe8e
출처 데이터셋
uspto-grants-1986_01
특허 번호
US04563288

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