참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Benzoyl Peroxide | HCID 7187 | — |
| 반응물 | Isobutyl Methacrylate | HCID 7352 | — |
| 반응물 | Lauryl Methacrylate | HCID 8906 | — |
| 반응물 | 1-Ethenyl-4-methylbenzene | HCID 12161 | — |
| 반응물 | 2-Methyldecane | HCID 23415 | — |
| 용매 | 2-Methylundecane | HCID 23459 | — |
| 생성물 | Isobutyl methacrylate vinyltoluene n-dodecyl methacrylate | HCID 86737663 | — |
반응 단계
A solution of 20.0 g of m-, p-vinyltoluene (mainly para-), 20.0 g of isobutyl methacrylate, 10 g of n-dodecyl methacrylate, 0.25 g of benzoyl peroxide (100%), and 25.0 g of isododecane or ISOPAR G (trade name) was introduced in a reaction pressure tube of about 100 ml. Nitrogen was bubbled through for 5 min. The pressure tube was sealed and immersed in an oil-bath of 80° C. After a reaction time of 16 h the viscous bright solution was admixed with 0.25 g of benzoyl peroxide and the pressure tube was sealed again and heated to 80° C. After a total reaction time of 40 h a very viscous transparent solution was obtained. The polymerization was quantitative and the polymer solution was diluted with fresh isododecane to a total weight of 250 g.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04259429 |
|---|
| 출처 데이터셋 | uspto-grants-1981_03 |
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| ORD ID | ord-536c6fe8653c4f088ea6928909a58478 |
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| 출처 메모 | uspto-grants-1981_03 |
|---|
