Water → HCID 20322157, 화합물

HRID 1287357노트

반응식

HRID 1287357 반응식
Cl[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[CH2:9][CH2:10][CH2:11][Cl:12].[C:13]([O-:16])(=[O:15])[CH3:14].[Na+].O>C(O)(=O)C>[Cl:12][CH2:11][CH2:10][CH2:9][C:4]1[CH:5]=[CH:6][CH:7]=[CH:8][C:3]=1[CH2:2][O:16][C:13](=[O:15])[CH3:14]

참가 물질

5

반응물 3

HCID 962WaterHCID 517045Sodium AcetateHCID 123739901-(Chloromethyl)-2-(3-chloropropyl)benzene

생성물 1

HCID 20322157HCID 20322157, 화합물

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

70 g (345 mmols) of 3-(2-Chloromethylphenyl)-propyl chloride (JACS 75, 2053 (1953)) and 50 g (0.61 mmol) of sodium acetate were heated to the boiling point while stirring in 250 ml of glacial acetic acid. It resulted from the thin layer chromatography that the reaction was finished after 41/2 hours. After cooling about 700 ml of water were added and the product was extracted with benzene. The organic phase was washed with water, dried and distilled off after evaporation of the solvent.

후처리

  1. customIt resulted from the thin layer chromatography that the reaction
  2. custom2 hours
  3. additionwere added
  4. extractionthe product was extracted with benzene
  5. washThe organic phase was washed with water
  6. customdried
  7. distillationdistilled off
  8. customafter evaporation of the solvent

출처 및 근거

ORD 기록
ord-ef7720a1dc5e4cf2900ce3ad6fe94177
출처 데이터셋
uspto-grants-1976_10
특허 번호
US03984459

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