참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Allene | HCID 10037 | — |
| 반응물 | Phenylacetylene | HCID 10821 | — |
| 반응물 | Propyne, mixed with propadiene | HCID 62152 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | Allene Phenylacetylene | HCID 86752504 | — |
반응 단계
In this example the starting monomers allene and phenylacetylene (HC≡C--O) are introduced into the catalyst mixture of Example 1 in a feed ratio of 62 to 38 (mole ratio). The polymerization conditions and catalyst are the same as in Example 1. After stirring at 60° C. for ten hours, a copolymer with a molecular weight of about 25,000 daltons (measured by GPC) is produced and can be isolated by precipitation to methanol. Given a starting amount of 0.5 g allene and 1.18 g phenylacetylene, the yield of copolymer will be 1.5 g, and have the formula: ##STR13##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05747618 |
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| 출처 데이터셋 | uspto-grants-1998_05 |
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| ORD ID | ord-6c267fdb1d9f4bf690b4a64c6c6aacaf |
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| 출처 메모 | uspto-grants-1998_05 |
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