Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trimethylsilyl cyanide → 4-Bromo-2-cyanopyridine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trimethylsilyl cyanide | HCID 82115 | — |
| 반응물 | 4-Bromopyridin-1-ium-1-olate | HCID 139708 | — |
| 생성물 | 4-Bromo-2-cyanopyridine | HCID 693283 | — |
반응 단계
The title compound was prepared from 4-bromopyridine-1-oxide (Rec. Trav. chim., 1951, 70, 581) and trimethylsilyl cyanide, using the procedure described in Chem. Pharm. Bull., 1985, 33, 565, and obtained as a solid (49% yield), m.p. 88°-93° C. Rf 0.53 (SS 11). Found: C,39.15; H,1.50; N,15.07. C6H3BrN2 requires C,39.37; E,1.65; N,15.30%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05750520 |
| 출처 데이터셋 | uspto-grants-1998_05 |
| ORD ID | ord-b9e28d64c47c4e2bbcdbe54b64ba0176 |
| 출처 메모 | uspto-grants-1998_05 |