Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Chloro-1,3,2-benzodioxaborole → o-Phenetidine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Chloro-1,3,2-benzodioxaborole | HCID 4136924 | — |
| 반응물 | tert-butyl-N-(2-ethoxyphenyl)carbamate | HCID 4935495 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | o-Phenetidine | HCID 7203 | 520.7% |
반응 단계
The reaction between 1.2 g (1.4 mmol) of tert-butyl-N-(2-ethoxyphenyl)carbamate (˜1.2 mmol/g) bonded on solid support 9 and 0.87 g (5.66 mmol, 4 eq) of 0.2 M B-chlorocatecholborane in anhydrous CH2Cl2 according to the procedure described hereinabove, followed by filtration and washing, gave 1 g of a brown powder (yield: 95%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07238693B2 |
| 출처 데이터셋 | uspto-grants-2007_07 |
| ORD ID | ord-4515da28b6fb40278be91db9bd8cc800 |
| 출처 메모 | uspto-grants-2007_07 |