Methylamine → 828242-89-3

HRID 1295736노트

반응식

HRID 1295736 반응식
[CH3:1][S:2][CH2:3][O:4][C:5]1[CH:6]=[C:7]([CH:10]=[CH:11][CH:12]=1)[CH:8]=O.[CH3:13][NH2:14]>CCO>[CH3:13][N:14]=[CH:8][C:7]1[CH:10]=[CH:11][CH:12]=[C:5]([O:4][CH2:3][S:2][CH3:1])[CH:6]=1

참가 물질

4

반응물 2

HCID 6329MethylamineHCID 714171123-[(Methylsulfanyl)methoxy]benzaldehyde

생성물 1

HCID 69507905828242-89-3

시약·촉매·용매 1

HCID 702Ethanol용매

반응 조건

온도
40 °C

실험 절차

3-Methylsulfanylmethoxy-benzaldehyde from step 1 (3.309 g, 18.16 mmol) was dissolved in EtOH (9 mL). MeNH2 (2.55 mL, 40% in H2O) was added and the mixture was heated to 40° C. for 30 min. Upon cooling, the mixture was concentrated in vacuo. The aqueous residue was diluted with isopropanol and then concentrated in vacuo. This was repeated twice more giving 3.55 g (quant) of a pale yellow oil.

후처리

  1. temperatureUpon cooling
  2. concentrationthe mixture was concentrated in vacuo
  3. additionThe aqueous residue was diluted with isopropanol
  4. concentrationconcentrated in vacuo
  5. customThis was repeated twice more giving 3.55 g (quant) of a pale yellow oil

출처 및 근거

ORD 기록
ord-1d7ba7712bc54ebab51e00a99045115a
출처 데이터셋
uspto-grants-2007_07
특허 번호
US07244738B2

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