참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Alpha-Methylstyrene | HCID 7407 | — |
| 반응물 | Benzenecarbodithioic acid | HCID 67141 | — |
| 용매 | Carbon Tetrachloride | HCID 5943 | — |
| 생성물 | Cumyl dithiobenzoate | HCID 11065602 | 32.6% |
반응 단계
A mixture of dithiobenzoic acid (10.59 g), a-methylstyrene (10 g) and carbon tetrachloride (40 mL) was heated at 70° C. for 4 hours. The resultant mixture was reduced to a crude oil which was purified by column chromatography (aluminium oxide (activity III), n-hexane eluent) to give 2-phenylprop-2-yl dithiobenzoate (5) (6.1 g, 32.6% yield) as a dark purple oil. 1H-nmr (CDCl3) d(ppm): 2.03 (s, 6H); 7.20-7.60 (m, 8H) and 7.86 (m, 2H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07250479B2 |
|---|
| 출처 데이터셋 | uspto-grants-2007_07 |
|---|
| ORD ID | ord-3cd00bcf174e4831bfb6f9b86e8987ab |
|---|
| 출처 메모 | uspto-grants-2007_07 |
|---|
