Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triethyl phosphite → Diethyl (Methoxymethyl)phosphonate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triethyl phosphite | HCID 31215 | — |
| 반응물 | Bromomethyl methyl ether | HCID 83093 | — |
| 생성물 | Diethyl (Methoxymethyl)phosphonate | HCID 11658394 | 98% |
반응 단계
To a sample of 17.90 mL (0.104 mol) of triethylphosphite at -78° C. under argon was added dropwise 8.50 mL (0.104 mol) of bromomethyl methyl ether. The mixture slowly warmed to RT and stirred for 24 h, when it was fractionally distilled (bp 100° C., 5 mm) to provide 16.22 g (98%) of title compound as a pale yellow oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05470845 |
| 출처 데이터셋 | uspto-grants-1995_11 |
| ORD ID | ord-b9f3818a0f834bd892592a8c40680371 |
| 출처 메모 | uspto-grants-1995_11 |