Water → Triethanolamine hydrochloride

HRID 129970노트

반응식

HRID 129970 반응식
S([Cl:5])(O)(=O)=O.O.[N:7]([CH2:14][CH2:15][OH:16])([CH2:11][CH2:12][OH:13])[CH2:8][CH2:9][OH:10]>>[ClH:5].[N:7]([CH2:14][CH2:15][OH:16])([CH2:11][CH2:12][OH:13])[CH2:8][CH2:9][OH:10]

참가 물질

4

반응물 3

HCID 962WaterHCID 7618TriethanolamineHCID 24638Chlorosulfonic acid

생성물 1

HCID 101814Triethanolamine hydrochloride

실험 절차

A suspension of 3.7 g of the sulfochloride of the formula (7) in 15 g of triethanolamine and 3 g of water is stirred at 150° for one hour. The excess solvent is substantially removed in vacuo at 120°-150° C., and 50 ml of isopropanol are added to the viscous residue. The precipitated product is filtered off with suction, washed repeatedly with isopropanol and taken up in approx. 40 ml of water. The cloudy solution is clarified by filtration with 0.2 g of active charcoal through a pressure filter. This gives an aqueous solution of the bistriethanolamine salt of the formula ##STR16## which still contains triethanolamine hydrochloride.

후처리

  1. customThe excess solvent is substantially removed in vacuo at 120°-150° C.
  2. addition50 ml of isopropanol are added to the viscous residue
  3. filtrationThe precipitated product is filtered off with suction
  4. washwashed repeatedly with isopropanol
  5. filtrationThe cloudy solution is clarified by filtration with 0.2 g of active charcoal through a pressure
  6. filtrationfilter

출처 및 근거

ORD 기록
ord-c8dfbb5099684f5fab825c642b5c6da5
출처 데이터셋
uspto-grants-1995_11
특허 번호
US05470990

반응 노트

불러오는 중…