Butanoic acid, 2,2,3,3,4,4,4-heptafluoro-, ethyl ester → 1-(2-Benzofuryl)-4,4,5,5,6,6,6-heptafluoro-1,3-hexanedione

HRID 130300

반응식

HRID 130300 반응식
[C:1]([C:4]1[O:5][C:6]2[CH:12]=[CH:11][CH:10]=[CH:9][C:7]=2[CH:8]=1)(=[O:3])[CH3:2].[F:13][C:14]([F:27])([F:26])[C:15]([F:25])([F:24])[C:16]([F:23])([F:22])[C:17](OCC)=[O:18]>>[O:5]1[C:6]2[CH:12]=[CH:11][CH:10]=[CH:9][C:7]=2[CH:8]=[C:4]1[C:1](=[O:3])[CH2:2][C:17](=[O:18])[C:16]([F:22])([F:23])[C:15]([F:24])([F:25])[C:14]([F:27])([F:26])[F:13]

참가 물질

3

반응물 2

HCID 9644Butanoic acid, 2,2,3,3,4,4,4-heptafluoro-, ethyl esterHCID 154352-Acetylbenzofuran

생성물 1

HCID 2551521-(2-Benzofuryl)-4,4,5,5,6,6,6-heptafluoro-1,3-hexanedione

실험 절차

The compound was synthesized according to example 1 using 2-acetylbenzofuran and ethyl heptafluorobutyrate as starting materials. The product was crystallized from petroleum ether. 1H NMR (CDCl3): 6.74 (s, 1 H); 7.35 (ddd, 1H, J=0.9 & 7.2 & 8.0 Hz); 7.52 (ddd, 1H, J=1.3 & 7.2 & 8.4 Hz); 7.58-7.61 (m, 1 H); 7.68 (d, 1H, J=0.9 Hz); 7.71-7.74 (m, 1 H). IR (film): 1614 (C═O); 1232 (C—F).

후처리

  1. customThe compound was synthesized
  2. customThe product was crystallized from petroleum ether

출처 및 근거

ORD 기록
ord-dddbe19f336049779a82549fca959976
출처 데이터셋
uspto-grants-2008_06
특허 번호
US07381567B2

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