2-(2,4-Dimethylcyclohex-3-en-1-yl)pyridine → HCID 69218660, 화합물

HRID 131088노트

반응식

HRID 131088 반응식
[CH3:1][CH:2]1[CH:7]=[C:6]([CH3:8])[CH2:5][CH2:4][CH:3]1[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][N:10]=1.C[C@@H]1C[C@H](C)CC[C@@H]1C1C=CC=CN=1>N1C=CC=CC=1>[CH3:1][C@@H:2]1[CH:7]=[C:6]([CH3:8])[CH2:5][CH2:4][C@H:3]1[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][N:10]=1

참가 물질

4

반응물 2

HCID 179724032-(2,4-Dimethylcyclohex-3-en-1-yl)pyridineHCID 692211552-[(1S,2R,4R)-2,4-Dimethylcyclohexyl]pyridine

생성물 1

HCID 69218660HCID 69218660, 화합물

시약·촉매·용매 1

HCID 1049Pyridine용매

실험 절차

The relative amounts of each individual isomer is dependent on the precise conditions used for their formation and whether the hydrogenation reaction is carried out on the mixture of isomers of 2-(2,4-dimethylcyclohex-3-en-1-yl)pyridine or an individual isomer thereof. For example, it has been found that when the hydrogenation reaction is performed on 2-[(1R,2S)-2,4-dimethylcyclohex-3-en-1-yl]pyridine, the major product formed in the resulting mixture of isomers of the pyridine of the invention is 2-[(1S,2R,4R)-2,4-dimethylcyclohexyl]pyridine. By contrast, hydrogenation of 2-[(1R,2R)-2,4-dimethylcyclohex-3-en-1-yl]pyridine conveniently gives a mixture of the 2-[(1R,2R,4R)-2,4-dimethylcyclohexyl]pyridine and 2-[(1R,2R,4S)-2,4-dimethylcyclohexyl]pyridine isomers as the major reaction product.

후처리

  1. customused for their formation and whether the hydrogenation reaction
  2. customthe hydrogenation reaction

출처 및 근거

ORD 기록
ord-25d3c85228984d3a81359e7477bed174
출처 데이터셋
uspto-grants-2008_06
특허 번호
US07384905B2

반응 노트

불러오는 중…