3,3'-Bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-oxydianiline → 4,4'-Diaminodiphenyl Ether

HRID 13437

반응식

HRID 13437 반응식
[OH:1][C:2]([C:11]1[CH:12]=[C:13]([CH:15]=[CH:16][C:17]=1[O:18][C:19]1[CH:25]=[CH:24][C:22]([NH2:23])=[CH:21][CH:20]=1)[NH2:14])([C:7]([F:10])([F:9])[F:8])[C:3]([F:6])([F:5])[F:4].[OH:26][C:27]([C:36]1[CH:37]=[C:38]([CH:40]=[CH:41][C:42]=1[O:43][C:44]1[CH:50]=[CH:49][C:47]([NH2:48])=[CH:46][C:45]=1C(C(F)(F)F)(O)C(F)(F)F)[NH2:39])([C:32]([F:35])([F:34])[F:33])[C:28]([F:31])([F:30])[F:29]>>[F:4][C:3]([F:6])([F:5])[C:2]([C:7]([F:10])([F:9])[F:8])=[O:1].[OH:26][C:27]([C:36]1[CH:37]=[C:38]([CH:40]=[CH:41][C:42]=1[O:43][C:44]1[CH:50]=[CH:49][C:47]([NH2:48])=[CH:46][CH:45]=1)[NH2:39])([C:28]([F:30])([F:29])[F:31])[C:32]([F:35])([F:34])[F:33].[O:18]([C:19]1[CH:25]=[CH:24][C:22]([NH2:23])=[CH:21][CH:20]=1)[C:17]1[CH:11]=[CH:12][C:13]([NH2:14])=[CH:15][CH:16]=1

참가 물질

5

반응물 2

HCID 866233913,3'-Bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-oxydianilineHCID 866233923-(1-Hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-oxydianiline

생성물 3

HCID 75794,4'-Diaminodiphenyl EtherHCID 12695HexafluoroacetoneHCID 866233923-(1-Hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-oxydianiline

실험 절차

The reaction liquid was found by gas chromatography (GC) analysis to contain 43.5% of the target compound, 3-(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4′-oxydianiline, 2.9% of 3,3′-bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4′-oxydianiline, and 46.6% of the total of various imines produced by the reaction of hexafluoroacetone with the amine moiety of 4,4′-oxydianiline.

후처리

  1. customThe reaction liquid

출처 및 근거

ORD 기록
ord-1876be99681d466c81135b49df4f546c
출처 데이터셋
uspto-grants-2010_06
특허 번호
US07728103B2

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