2-Acetylthiophene → 1,3-Hexanedione, 4,4,5,5,6,6,6-heptafluoro-1-(2-thienyl)-

HRID 1348528

반응식

HRID 1348528 반응식
[C:1]([C:4]1[S:5][CH:6]=[CH:7][CH:8]=1)(=[O:3])[CH3:2].[F:9][C:10]([F:23])([F:22])[C:11]([F:21])([F:20])[C:12]([F:19])([F:18])[C:13](OCC)=[O:14]>>[F:18][C:12]([F:19])([C:11]([F:20])([F:21])[C:10]([F:9])([F:22])[F:23])[C:13](=[O:14])[CH2:2][C:1]([C:4]1[S:5][CH:6]=[CH:7][CH:8]=1)=[O:3]

참가 물질

3

반응물 2

HCID 69202-AcetylthiopheneHCID 9644Butanoic acid, 2,2,3,3,4,4,4-heptafluoro-, ethyl ester

생성물 1

HCID 684111,3-Hexanedione, 4,4,5,5,6,6,6-heptafluoro-1-(2-thienyl)-

실험 절차

The compound was synthesized according to example 1 using 2-acetyl-thiophene and ethyl heptafluorobutyrate as starting materials. 1H NMR (CDCl3): 6.49 (s, 1 H); 7.21 (dd, 1 H, J=3.8 & 5.1); 7.77 (dd, 1 H, J=1.2 & 5.1 Hz); 7.85 (dd, 1 H, J=1.2 & 3.8 Hz). IR (film): 1589 (C═O); 1230 (C—F).

후처리

  1. customThe compound was synthesized

출처 및 근거

ORD 기록
ord-4cd34ebc3a174a06b6c043dac224b55d
출처 데이터셋
uspto-grants-2007_05
특허 번호
US07211440B2

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