참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Iodobenzene | HCID 11575 | — |
| 반응물 | N,N-Dimethylethylenediamine | HCID 66053 | — |
| 시약 | Cesium carbonate | HCID 10796 | — |
| 촉매 | 1,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(1,1-diphenylphosphine) | HCID 636044 | — |
| 촉매 | Bis(dibenzylideneacetone)palladium | HCID 9811564 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | N-(2-(Dimethylamino)ethyl)aniline | HCID 81206 | 0% |
반응 단계
In a 50 mL round-bottomed flask (t=g) was unsym-Dimethylethylenediamine (1.080 mL, 9.80 mmol), Iodobenzene (0.549 mL, 4.90 mmol), and TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) (0.449 g, 0.49 mmol)Cesium carbonate (2.396 g, 7.35 mmol) andCesium carbonate (2.396 g, 7.35 mmol) were added. in DMF (10 mL) ([VOLUME]) to give a brown suspension. Reaction stirred over night at 100°C. no reaction.
출처 및 근거
| 출처 데이터셋 | 750 AstraZeneca ELN dataset |
|---|
| ORD ID | ord-6eea29be7d4b47c5893b1e243ef41836 |
|---|
| 출처 메모 | 750 AstraZeneca ELN dataset |
|---|
