Paraoxon → 4-Nitrophenol

HRID 1350614

반응식

HRID 1350614 반응식
[CH3:1][CH2:2][O:3][P:4]([O:9][C:10]1[CH:11]=[CH:12][C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=1)([O:6][CH2:7][CH3:8])=[O:5]>CO>[P:4]([O:9][CH3:10])([O:6][CH2:7][CH3:8])([O:3][CH2:2][CH3:1])=[O:5].[CH:12]1[C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=[C:10]([OH:9])[CH:11]=1

참가 물질

4

반응물 1

HCID 9395Paraoxon

생성물 2

HCID 9804-NitrophenolHCID 120420Diethyl methyl phosphate

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

Paraoxon, when placed in an appropriately buffered methanol solution containing La3+ions held in a sspH region between 7 and 11, underwent rapid methanolysis at ambient temperature to produce diethyl methyl phosphate and p-nitrophenol. A detailed reaction scheme is given in Scheme 1.

후처리

  1. additioncontaining La3+ions
  2. customheld in a sspH region between 7 and 11, underwent rapid methanolysis at ambient temperature

출처 및 근거

ORD 기록
ord-1a7bc8fdc5514d6f949b478e0e4b72f2
출처 데이터셋
uspto-grants-2007_05
특허 번호
US07214836B2

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