Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Thiophosgene → 3-Phenoxyphenylisothiocyanate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Thiophosgene | HCID 10040 | — |
| 반응물 | 3-Phenoxyaniline | HCID 77135 | — |
| 반응물 | Ethyl acetate hexane | HCID 21226206 | — |
| 용매 | Acetone | HCID 180 | — |
| 생성물 | 3-Phenoxyphenylisothiocyanate | HCID 22041281 | — |
반응 단계
To a stirring solution of 3-phenoxyaniline (185 mg, 1.0 mmol) in acetone (4.0 mL) at 0° C. was added thiophosgene (0.23 mL, 3.0 mmol) and the resulting reaction maintained for 30 min. The reaction determined complete by TLC (4:1 hexane/EtOAc). The reaction was concentrated, azeotroped with toluene and taken on without further purification.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07728010B2 |
| 출처 데이터셋 | uspto-grants-2010_06 |
| ORD ID | ord-b272333b6f17485f927833b273755ad7 |
| 출처 메모 | uspto-grants-2010_06 |