Bis(trimethylstannyl)indene → HCID 178477784, 화합물

HRID 1354511노트

반응식

HRID 1354511 반응식
[Cl-:1].[Cl-].[Cl-].[CH:4]1([Zr+3:9])[CH:8]=[CH:7][CH:6]=[CH:5]1.[CH3:10][Sn:11]([C:14]1[CH:15]([Sn](C)(C)C)[C:16]2[C:21]([CH:22]=1)=[CH:20][CH:19]=[CH:18][CH:17]=2)([CH3:13])[CH3:12]>C1(C)C=CC=CC=1>[Cl-:1].[Cl-:1].[CH3:10][Sn:11]([C:14]1[CH:15]([Zr+2:9][CH:4]2[CH:8]=[CH:7][CH:6]=[CH:5]2)[C:16]2[C:21]([CH:22]=1)=[CH:20][CH:19]=[CH:18][CH:17]=2)([CH3:13])[CH3:12]

참가 물질

4

반응물 2

HCID 69432104Bis(trimethylstannyl)indeneHCID 178478629HCID 178478629, 화합물

생성물 1

HCID 178477784HCID 178477784, 화합물수율 177.1%

시약·촉매·용매 1

HCID 1140Toluene용매2회

실험 절차

Cyclopentadienylzirconium trichloride (CpZrCl3, 3.94 g, 15.0 mmol) which was slurrified by adding toluene of 70 ml was added into the mixed solution including bis(trimethylstannyl)indene (6.75 g, 15.28 mmol) and toluene of 100 ml, and then reacted for 21 hours at 85° C. Yellowish (trimethylstannyl-indenyl)(cyclopentadienyl)zirconium dichloride compound (6.71 g, yield: 86%) was obtained by a series of processes, such as removing toluene from reactant, slurrifying the obtained solid by adding hexane (100 ml) and filtering the slurry.

후처리

  1. additionwas added into the mixed solution
  2. customreacted for 21 hours at 85° C

출처 및 근거

ORD 기록
ord-3a68c936c1b949759705c002a0c1a4d3
출처 데이터셋
uspto-grants-2007_05
특허 번호
US07223824B2

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