1-Bromohexane → HCID 11732181, 화합물

HRID 1358062노트

반응식

HRID 1358062 반응식
[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

참가 물질

3

반응물 2

HCID 81011-BromohexaneHCID 2519872,7-Dichlorofluorene

생성물 1

HCID 11732181HCID 11732181, 화합물수율 91%

실험 절차

2,7-Dichloro-9,9-di(l-hexyl)fluorene was prepared from 2,7-dichlorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield; melting point 66° C. to 67° C. HPLC analysis showed that the sample was 99 percent or greater pure and the spectral data confirmed the title structure.

후처리

  1. customas colorless crystals (recrystallized from hexane) in 91 percent yield

출처 및 근거

ORD 기록
ord-adbe979421204758897b7f3233f77017
출처 데이터셋
uspto-grants-2003_07
특허 번호
US06593450B2

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