Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Methyl-2-nitroanisole → 2-Methoxy-6-methylaniline
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Methyl-2-nitroanisole | HCID 79291 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 2-Methoxy-6-methylaniline | HCID 459249 | — |
반응 단계
A solution of 1-methoxy-3-methyl-2-nitrobenzene (15.04 g, 0.09 mol) in ethanol (250 ml) was hydrogenated over 10% palladium on charcoal (4 g) at atmospheric pressure and at room temperature, for 18 h. The catalyst was removed by filtration, and the filtrate evaporated under reduced pressure to leave the title compound (D28) as an amber oil, which crystallised on standing (11.18 g, 91%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06599904B2 |
| 출처 데이터셋 | uspto-grants-2003_07 |
| ORD ID | ord-6d7e7e529731450082821b906b6e9160 |
| 출처 메모 | uspto-grants-2003_07 |