2-(Ethoxymethylene)propanedinitrile → 1H-Benzimidazole-6-carbonitrile
반응식
[NH2:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[NH2:10])[C:5]#[N:6].[CH2:11](OC=C(C#N)C#N)C>C(O)(C)C>[N:10]1[C:9]2[CH:8]=[CH:7][C:4]([C:5]#[N:6])=[CH:3][C:2]=2[NH:1][CH:11]=1참가 물질
4
실험 절차
A mixture of 3,4-diaminobenzonitrile (2) (1.0 g) and (ethoxymethylene)malononitrile (1.4 g) was refluxed in 50 mL of isopropyl alcohol for 16 h. The mixture was concentrated in vacuo to provide the title compound, 3H-benzo[d]imidazole-5-carbonitrile (3).
후처리
- concentrationThe mixture was concentrated in vacuo
출처 및 근거
- ORD 기록
- ord-d9aadab0f5414477931c8f7a1a189282
- 출처 데이터셋
- uspto-grants-2011_02
- 특허 번호
- US07884109B2
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