Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cyclohexanesulfonamide → 2,2-Dimethylpropane-1-sulfonamide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cyclohexanesulfonamide | HCID 75536 | — |
| 반응물 | HCID 178418809 | HCID 178418809 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 2,2-Dimethylpropane-1-sulfonamide | HCID 18348400 | 27% |
반응 단계
Following the procedure for the preparation of cyclohexylsulfonamide, 49 mL (37 mmol) of 0.75M neopentylmagnesium chloride (Alfa) in diethyl ether was converted to 1.52 g (27%) of the desired product as a white solid. 1H NMR (CDCl3) δ 1.17 (s, 9H), 3.12 (s, 2H), 4.74 (brs, 2H); 13C NMR (CDCl3) δ 29.46, 31.51, 67.38; MS m/e 150 (M−1)−.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07888464B2 |
| 출처 데이터셋 | uspto-grants-2011_02 |
| ORD ID | ord-80a4c0f6e45e40c887f0c3d28f8e133d |
| 출처 메모 | uspto-grants-2011_02 |