Water → HCID 23667830, 화합물

HRID 1368006

반응식

HRID 1368006 반응식
Br[CH2:2][CH:3]([Br:8])[CH2:4][CH2:5][CH2:6][CH3:7].[S:9]([O-:12])([O-:11])=[O:10].[Na+:13].[Na+].O>C(O)C>[Br:8][CH:3]([CH2:4][CH2:5][CH2:6][CH3:7])[CH2:2][S:9]([O-:12])(=[O:11])=[O:10].[Na+:13]

참가 물질

5

반응물 3

HCID 962WaterHCID 24437Sodium SulfiteHCID 102451Hexane, 1,2-dibromo-

생성물 1

HCID 23667830HCID 23667830, 화합물수율 50%

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

1,2-Dibromohexane (1.22 g, 5.0 mmol) was added to a solution of 0.6 g (5 mmol) of sodium sulfite in 20 mL of a 1:1 mixture of water and ethanol, and the resulting mixture was refluxed for 24 hours with vigorous stirring. The ethanol was then removed by distillation and the residual solution was allowed to stand at room temperature, whereupon white crystals precipitated. The crystals were filtered off under reduced pressure, washed with ether and dried to give 0.67 g (2.5 mmol) of the desired substance, namely sodium 2-bromohexylsulfonate (yield 50%).

후처리

  1. temperaturethe resulting mixture was refluxed for 24 hours with vigorous stirring
  2. customThe ethanol was then removed by distillation
  3. customto stand at room temperature, whereupon white crystals
  4. customprecipitated
  5. filtrationThe crystals were filtered off under reduced pressure
  6. washwashed with ether
  7. customdried

출처 및 근거

ORD 기록
ord-18c82fc8e368498aafde06e033ffe71f
출처 데이터셋
uspto-grants-2003_06
특허 번호
US06572839B2

연결된 노트

불러오는 중…