Aniline → HCID 18516901, 화합물

HRID 1370062노트

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HRID 1370062 반응식
[N:1]1([CH2:6][CH2:7][O:8][C:9]2[CH:14]=[CH:13][C:12]([N+:15]([O-])=O)=[CH:11][CH:10]=2)[CH:5]=[CH:4][N:3]=[N:2]1.NC1C=CC=CC=1>[Pd]>[N:1]1([CH2:6][CH2:7][O:8][C:9]2[CH:14]=[CH:13][C:12]([NH2:15])=[CH:11][CH:10]=2)[CH:5]=[CH:4][N:3]=[N:2]1

참가 물질

4

반응물 2

HCID 6115AnilineHCID 185169874-[2-(1,2,3-Triazol-1-yl)ethoxy]nitrobenzene

생성물 1

HCID 18516901HCID 18516901, 화합물

시약·촉매·용매 1

HCID 23938Palladium촉매

실험 절차

4-[2-(1,2,3-Triazol-1-yl)ethoxy]aniline was prepared from 4-[2-(1,2,3-triazol-1-yl)ethoxy]nitrobenzene (5.98 g, 25.5 mmol) and 10% palladium on charcoal (1.5 g) in a manner similar to the aniline intermediate of Example 12 to give the desired material (4.91 g) as a yellow solid m.p. 141°. δH (CDCl3) 7.69 (1H, d, J 0.5 Hz), 7.62 (1H, d J 0.5 Hz), 6.65 (2H, d, J 5.8 Hz), 6.58 (2H, d, J 5.8 Hz), 4.71 (2H, t, J 5.0 Hz), 4.24 (2H, t, J 5.0 Hz) and 3.43 (2H, s).

출처 및 근거

ORD 기록
ord-cf4ea7fe4c5c4e2392c5316b7e6c84ab
출처 데이터셋
uspto-grants-2003_06
특허 번호
US06579983B1

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