Chlorotrimethylsilane → Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]-

HRID 1370676

반응식

HRID 1370676 반응식
[CH3:1][CH:2]([C:4](=[O:8])[CH:5]([CH3:7])[CH3:6])[CH3:3].[CH3:9][Si:10](Cl)([CH3:12])[CH3:11]>>[CH3:1][C:2](=[C:4]([O:8][Si:10]([CH3:12])([CH3:11])[CH3:9])[CH:5]([CH3:7])[CH3:6])[CH3:3]

참가 물질

3

반응물 2

HCID 6397ChlorotrimethylsilaneHCID 112712,4-Dimethyl-3-pentanone

생성물 1

HCID 11095327Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]-

실험 절차

Reaction between 2,4-dimethyl-3-pentanone(1.2.4.3), trimethylsilyl chloride, and base gave 2,4-dimethyl-3-trimethysilyloxy-2-pentene(1.2.4.4) which was reacted with 1-fluoropyridinium triflate(1.2.4.5) to form 2,4-dimethyl-2-fluoro-3-pentanone(1.2.4.6). This product was reacted with (CH3)3S(O)+I− to form the title compound (1.2.4.2).

출처 및 근거

ORD 기록
ord-f2913291a08f4e8a98d7e005389c8c9b
출처 데이터셋
uspto-grants-2003_06
특허 번호
US06583182B1

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