1-Pentanol → Amyl oleate

HRID 13733

반응식

HRID 13733 반응식
[C:1]([O:20][CH2:21][CH3:22])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH2:23](O)[CH2:24][CH2:25]CC>CCOCC>[C:1]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

참가 물질

4

반응물 2

HCID 62761-PentanolHCID 5363269Ethyl Oleate

생성물 1

HCID 5354230Amyl oleate수율 91%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

A mixture containing Catalyst A or B (0.05 g) and ethyl oleate (1.55 g, 5 mmol) and pentanol (10 ml) was refluxed with stirring for 40 h. On cooling ether (30 ml) was added and the catalyst was filtered off. The organic washings were combined and concentrated to give pentyl oleate as an oil (1.6 g, 91% yield).

후처리

  1. temperaturewas refluxed
  2. additionwas added
  3. filtrationthe catalyst was filtered off
  4. concentrationconcentrated

출처 및 근거

ORD 기록
ord-c891a9a360914f4b89c8c19dfb2ab01a
출처 데이터셋
uspto-grants-2010_06
특허 번호
US07728159B2

연결된 노트

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