(+)-Solketal → (2S)-2,3-Bis(nitrooxy)propan-1-ol

HRID 1374068

반응식

HRID 1374068 반응식
CC1(C)O[C@@H](CO)CO1.CC(C)(C)[Si](C1C=CC=CC=1)(C1C=CC=CC=1)OC[C@@H](O)CO.[N+:33]([O:36][C@@H:37]([CH2:40][O:41][N+:42]([O-:44])=[O:43])[CH2:38][OH:39])([O-:35])=[O:34]>>[N+:33]([O:36][C@H:37]([CH2:40][O:41][N+:42]([O-:44])=[O:43])[CH2:38][OH:39])([O-:35])=[O:34]

참가 물질

4

반응물 3

HCID 736057(+)-SolketalHCID 10806357(2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diolHCID 73416231HCID 73416231, 화합물

생성물 1

HCID 73416232(2S)-2,3-Bis(nitrooxy)propan-1-ol

실험 절차

The title compound was prepared in four steps from ((4S)-2,2-dimethyl-1,3-dioxolan-4-yl)methan-1-ol following the procedures for Examples 5a, 5b, 5c, and 5d.

출처 및 근거

ORD 기록
ord-131d5ba558c541dfbb89c27901adb7c8
출처 데이터셋
uspto-grants-2007_01
특허 번호
US07163958B2

연결된 노트

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