m-Chloroperbenzoic acid → 2-Methylsulphinyl-4-methylamino-5-methyl-pyrimidine

HRID 1374648노트

반응식

HRID 1374648 반응식
[CH3:1][S:2][C:3]1[N:8]=[C:7]([NH:9][CH3:10])[C:6]([CH3:11])=[CH:5][N:4]=1.ClC1C=C(C=CC=1)C(OO)=[O:17].C(Cl)Cl.CO>C(Cl)Cl>[CH3:1][S:2]([C:3]1[N:8]=[C:7]([NH:9][CH3:10])[C:6]([CH3:11])=[CH:5][N:4]=1)=[O:17]

참가 물질

5

반응물 3

HCID 70297m-Chloroperbenzoic acidHCID 241191HCID 241191, 화합물HCID 21226129Dichloromethane methanol

생성물 1

HCID 210776012-Methylsulphinyl-4-methylamino-5-methyl-pyrimidine

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

Prepared from 2-methylsulphenyl-4-methylamino-5-methyl-pyrimidine by reacting with 3-chloro-peroxybenzoic acid in methylene chloride, Rf value: 0.23 (silica gel; methylene chloride/methanol/ conc. aqueous ammonia=20:1:0.1)

출처 및 근거

ORD 기록
ord-ede1d5379e934237a600435a4149b0e6
출처 데이터셋
uspto-grants-2007_01
특허 번호
US07166599B2

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