Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
5-(2-Butyl-1,3-dithiolan-2-yl)benzene-1,3-diol → 5-(1-Cyclopentyl-1-methyl-ethyl)-benzene-1,3-diol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 5-(2-Butyl-1,3-dithiolan-2-yl)benzene-1,3-diol | HCID 317695 | — |
| 반응물 | 1-(1-Cyclopentyl-1-methyl-ethyl)-3,5-dimethoxy-benzene | HCID 66886128 | — |
| 용매 | Diethylether hexane | HCID 21584099 | — |
| 생성물 | 5-(1-Cyclopentyl-1-methyl-ethyl)-benzene-1,3-diol | HCID 45093623 | — |
반응 단계
Compound 20 was prepared from Compound 13 using the same procedure as described above for Compound 16. Yield 1.29 g (72.9%) as a viscous oil. Rf=0.28 (hexane:diethyl ether 6:4); 1H NMR δ 6.44 (d, J=2.1 Hz, 2H), 6.20 (t, J=2.1 Hz, 1H), 5.70 (br s, 2H), 2.02–1.98 (m, 1H), 1.57–1.35 (m, 6H), 1.18 (s, 6H); 13C NMR δ 156.22, 154.66, 105.10, 99.83, 53.24, 50.33, 36.21, 24.99, 24.75; MS: (ESI, Neg.) m/z 219 ([M−H]−).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07169942B2 |
| 출처 데이터셋 | uspto-grants-2007_01 |
| ORD ID | ord-89f2b02163ec4d999d1c7fed66ebf277 |
| 출처 메모 | uspto-grants-2007_01 |