Benzyl Bromide → HCID 22902705, 화합물

반응식

[CH:1]1([O:7][N:8]2[C:13]([CH3:15])([CH3:14])[CH2:12][C:11](=[N:16][OH:17])[CH2:10][C:9]2([CH3:19])[CH3:18])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH2:20](Br)[C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>>[CH2:20]([N:16]([CH:11]1[CH2:12][C:13]([CH3:14])([CH3:15])[N:8]([O:7][CH:1]2[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]2)[C:9]([CH3:19])([CH3:18])[CH2:10]1)[OH:17])[C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1

참가 물질

반응물 2

HCID 7498Benzyl Bromide

HCID 22902739HCID 22902739, 화합물

생성물 1

HCID 22902705HCID 22902705, 화합물수율 50%

실험 절차

Following the procedure of Example 1, the title compound is prepared from 1-cyclohexyloxy-2,2,6,6-tetra-methylpiperidin-4-one oxime (3.7 g, 13 mmol) and benzyl bromide (2.4 g, 14 mmol) in a 50% yield to give 2.3 g of product as white crystals melting at 133° C. after recrystalization from ethanol.

출처 및 근거

ORD 기록: ord-c6c21ce8275540b8a4bdbdd0abf89d4e
출처 데이터셋: uspto-grants-1997_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05668199

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