Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triphenylphosphine → Diphenyl-cis-9-octadecenyloxysilanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triphenylphosphine | HCID 11776 | — |
| 반응물 | Diphenylsilanediol | HCID 13693 | — |
| 반응물 | Diisopropyl diazene-1,2-dicarboxylate | HCID 75555 | — |
| 반응물 | Oleyl Alcohol | HCID 5284499 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Diphenyl-cis-9-octadecenyloxysilanol | HCID 70264695 | — |
반응 단계
Diphenyl-cis-9-octadecenyloxysilanol is prepared under Mitsunobu conditions from 2 g (9.25 mmol) of diphenylsilanediol, 2.08 ml (4.62 mmol) of cis-9-octadecen-1-ol, 2.45 g (9.25 mmol) of triphenylphosphine and 1.88 ml (9.25 mmol) of azodicarboxylic acid diisopropyl ester in 40 ml of tetrahydrofuran analogously to Step 1.3, Variant a.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05670491 |
| 출처 데이터셋 | uspto-grants-1997_09 |
| ORD ID | ord-4c488500b26243a9877553911f236e54 |
| 출처 메모 | uspto-grants-1997_09 |