4-Fluoro-3-nitrobenzotrifluoride → 2,4-Hexadiyn-1,6-diol bis-(2-nitro-4-trifluoromethylphenyl)ether

HRID 1380270

반응식

[CH2:1]([OH:8])[C:2]#[C:3][C:4]#[C:5][CH2:6][OH:7].F[C:10]1[CH:15]=[CH:14][C:13]([C:16]([F:19])([F:18])[F:17])=[CH:12][C:11]=1[N+:20]([O-:22])=[O:21]>>[CH2:1]([OH:8])[C:2]#[C:3][C:4]#[C:5][CH2:6][OH:7].[N+:20]([C:11]1[CH:12]=[C:13]([C:16]([F:19])([F:18])[F:17])[CH:14]=[CH:15][C:10]=1[O:8][C:1]1[CH:6]=[CH:5][C:4]([C:16]([F:19])([F:18])[F:17])=[CH:3][C:2]=1[N+:20]([O-:22])=[O:21])([O-:22])=[O:21]

참가 물질

반응물 2

HCID 677784-Fluoro-3-nitrobenzotrifluoride

HCID 94973Diacetylene glycol

생성물 1

HCID 886877102,4-Hexadiyn-1,6-diol bis-(2-nitro-4-trifluoromethylphenyl)ether

실험 절차

Reaction of 2,4-hexadiyne-1,6-diol (1 g) with 4-fluoro-3-nitro-benzotrifluoride (4 g.) following the procedure of Example 3 yielded the desired product. Recrystallization from ethanol gave pale yellow needles. (1.1 g., 25%) m.p. 137° C. I.R. (KBr): 1620(NO2), 1120 682 (CF3)cm-1.

출처 및 근거

ORD 기록: ord-3c586a1186c748db81cc0bdcf05a56e3
출처 데이터셋: uspto-grants-1986_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04581315

연결된 노트

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