Chloranil → HCID 3335773, 화합물

HRID 1380282노트

반응식

HRID 1380282 반응식
[C:1]1(Cl)[C:7](=[O:8])[C:6](Cl)=[C:5](Cl)[C:3](=[O:4])[C:2]=1Cl.[C:13]1(=[O:23])[NH:17][C:16](=[O:18])[C:15]2=[CH:19][CH:20]=[CH:21][CH:22]=[C:14]12.[K]>C(#N)C.CN(C)C=O>[C:13]1(=[O:23])[N:17]([C:1]2[C:7](=[O:8])[C:6]([N:17]3[C:13](=[O:23])[C:14]4=[CH:22][CH:21]=[CH:20][CH:19]=[C:15]4[C:16]3=[O:18])=[C:5]([N:17]3[C:13](=[O:23])[C:14]4=[CH:22][CH:21]=[CH:20][CH:19]=[C:15]4[C:16]3=[O:18])[C:3](=[O:4])[C:2]=2[N:17]2[C:16](=[O:18])[C:15]3=[CH:19][CH:20]=[CH:21][CH:22]=[C:14]3[C:13]2=[O:23])[C:16](=[O:18])[C:15]2=[CH:19][CH:20]=[CH:21][CH:22]=[C:14]12

참가 물질

5

반응물 2

HCID 8371ChloranilHCID 24194345Phthalimide potassium salt

생성물 1

HCID 3335773HCID 3335773, 화합물

시약·촉매·용매 2

HCID 6228Dimethylformamide용매HCID 6342Acetonitrile용매

실험 절차

A suspension of chloranil (10.00 g, 0.04 mole) and potassium phthalimide (30.00 g, 0.16 mole) in acetonitrile is refluxed overnight. The deep purple solution is allowed to cool and then filtered, yielding a tan solid. This solid is then boiled in approximately 200 ml of dimethylformamide for ten minutes. The hot DMF suspension is then filtered yielding a white thixotropic solid.

후처리

  1. temperatureis refluxed overnight
  2. temperatureto cool
  3. filtrationfiltered
  4. customyielding a tan solid
  5. filtrationThe hot DMF suspension is then filtered
  6. customyielding a white thixotropic solid

출처 및 근거

ORD 기록
ord-4f104052e77947099da9ed2864aa4cf1
출처 데이터셋
uspto-grants-1986_04
특허 번호
US04581349

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