Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triethylamine → 2,4,8,10-Tetra-t-butyl-6-phenyl-12H-dibenzo[d,g][1,3,2]dioxasilocin
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | Dichloro(phenyl)silane | HCID 74207 | — |
| 반응물 | 2,2'-Methylenebis(4,6-di-tert-butylphenol) | HCID 84391 | — |
| 생성물 | 2,4,8,10-Tetra-t-butyl-6-phenyl-12H-dibenzo[d,g][1,3,2]dioxasilocin | HCID 131714147 | 64.3% |
반응 단계
Utilizing the procedure of Example 1, this compound is prepared from 17.7 grams (0.1 mole) of dichlorophenylsilane, 42.5 grams (0.1 mole) of 2,2'-methylenebis(4,6-di-t-butylphenol) and 20.2 grams (0.20 mole) of triethylamine. Recrystallization twice from acetonitrile-toluene yields 34.0 grams (64% yield) of product as an off white powder, mp 153°-156° C.; IR: 2200 cm-1SiH.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04582870 |
| 출처 데이터셋 | uspto-grants-1986_04 |
| ORD ID | ord-5db59391d9ff4c1d9370aab3ee4b2a84 |
| 출처 메모 | uspto-grants-1986_04 |