Chlorine → 1-Chloro-4-(trifluoromethoxy)benzene

HRID 1380715

반응식

HRID 1380715 반응식
[Cl:1]Cl.[N+]([C:6]1[CH:11]=[CH:10][C:9]([O:12][C:13]([F:16])([F:15])[F:14])=[CH:8][CH:7]=1)([O-])=O>>[Cl:1][C:6]1[CH:11]=[CH:10][C:9]([O:12][C:13]([F:16])([F:15])[F:14])=[CH:8][CH:7]=1

참가 물질

3

반응물 2

HCID 24526Chlorine2회HCID 5224051-Nitro-4-(trifluoromethoxy)benzene

생성물 1

HCID 27772731-Chloro-4-(trifluoromethoxy)benzene수율 83%

실험 절차

Chlorine and p-nitrotrifluoromethoxybenzene (10.7 parts) were fed simultaneously at a molar ratio of 3:1, Cl2 :organic reactant, into a vapor phase reactor maintained at 300° to 320° C. over a 30 minute period to yield 8.2 parts of p-chlorotrifluoromethoxybenzene (83% yield). The structure of the product was confirmed by gas chromatographic-mass spectrum and F19 nuclear magnetic resonance analysis.

후처리

  1. temperatureorganic reactant, into a vapor phase reactor maintained at 300° to 320° C. over a 30 minute period

출처 및 근거

ORD 기록
ord-4b28e585bc67489cb3e1fb911d51625c
출처 데이터셋
uspto-grants-1986_04
특허 번호
US04582948

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