1-Anthracenecarboxylic Acid → (10-Bromo-1-anthracenyl)methanol

HRID 1381778노트

반응식

HRID 1381778 반응식
[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[C:16](O)=[O:17].C1(C(O)=O)C2C(=CC3C(C=2)=CC=CC=3)C=CC=1.C1(CO)C2C(=CC3C(C=2)=CC=CC=3)C=CC=1>C1COCC1>[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[CH2:16][OH:17]

참가 물질

5

반응물 3

HCID 1507891-Anthracenecarboxylic AcidHCID 12695455(Anthracen-1-yl)methanolHCID 21276215HCID 21276215, 화합물

생성물 1

HCID 13375398(10-Bromo-1-anthracenyl)methanol

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

10-Bromo-1-anthracenecarboxylic acid made from 1-anthracenecarboxylic acid (15B) by the procedure of E. Barnett, J. W. Cook, and H. H. Grainger, Ber. 57 B, 1775 (1924), was reduced with BH3 in THF by the procedure outlined in 15C to give (10-bromo-1-anthracenyl)methanol mp 125°-127°, (EtOAc/hexane), (C, H, Br).

출처 및 근거

ORD 기록
ord-f4db24597f4541fe96f0b2c49abe5d20
출처 데이터셋
uspto-grants-1989_02
특허 번호
US04803221

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