1H-Cyclopenta[l]phenanthrene → 2,3-Dihydro-1H-cyclopenta[l]phenanthrene

HRID 1386571노트

반응식

HRID 1386571 반응식
[CH2:1]1[C:5]2[C:6]3[C:11]([C:12]4[CH:13]=[CH:14][CH:15]=[CH:16][C:17]=4[C:4]=2[CH:3]=[CH:2]1)=[CH:10][CH:9]=[CH:8][CH:7]=3.[H][H]>[Pd].C1(C)C=CC=CC=1>[CH2:3]1[C:4]2[C:17]3[C:12]([C:11]4[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=4[C:5]=2[CH2:1][CH2:2]1)=[CH:13][CH:14]=[CH:15][CH:16]=3

참가 물질

5

반응물 2

HCID 118061071H-Cyclopenta[l]phenanthreneHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 6128122,3-Dihydro-1H-cyclopenta[l]phenanthrene

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 1140Toluene용매

실험 절차

A mixture of 2 g cyclopentaphenanthrene, 0.2 g 10% palladium on carbon and 50 mL toluene was stirred under hydrogen (69 kPa) until hydrogen uptake ceased, about 48 h. Catalyst was removed by filtration through diatomaceous earth and the filtrate evaporated. The crude product remaining weighed 1.97 g. It was further purified by recrystallization from heptane at −40° C. to give 1.8 g colorless plates. Spectroscopic and chemical analysis confirmed the identity of the desired compound.

후처리

  1. customCatalyst was removed by filtration through diatomaceous earth
  2. customthe filtrate evaporated
  3. customIt was further purified by recrystallization from heptane at −40° C.
  4. customto give 1.8 g colorless plates

출처 및 근거

ORD 기록
ord-5280e33ae0604b8eae60aa32e05eeae8
출처 데이터셋
uspto-grants-2001_07
특허 번호
US06265512B1

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