Tert-Butylamine → 1-(bromomethyl)-N-(1,1-dimethylethyl)-1,1-dimethylsilanamine
반응식
[Br:1][CH2:2][Si:3](Cl)([CH3:5])[CH3:4].[C:7]([NH2:11])([CH3:10])([CH3:9])[CH3:8]>CCOCC>[Br:1][CH2:2][Si:3]([CH3:5])([CH3:4])[NH:11][C:7]([CH3:10])([CH3:9])[CH3:8]참가 물질
4
실험 절차
To a stirred solution of 10.00 g (53.32 mmol) of (bromomethyl)chlorodimethylsilane in 200 ml, of diethylether a solution of 7.80 g (106.64 mmol) of t-butyl amine in 10 mL of ether was added. A white solid deposited instantaneously. The reaction mixture was stirred overnight, filtered through a medium frit and the solvent was removed under reduced pressure to give 11.06 g of colorless liquid. Yield 93 percent.
후처리
- filtrationfiltered through a medium frit
- customthe solvent was removed under reduced pressure
출처 및 근거
- ORD 기록
- ord-affda961a3a0478f98223a0d82b9e140
- 출처 데이터셋
- uspto-grants-2001_07
- 특허 번호
- US06268444B1
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