Water → Bis(diphenylmethyl) ether

HRID 1388240노트

반응식

HRID 1388240 반응식
Cl[CH:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[OH2:15]>>[CH:2]([O:15][CH:2]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

참가 물질

3

반응물 2

HCID 962Water2회HCID 7035Chlorodiphenylmethane

생성물 1

HCID 11323Bis(diphenylmethyl) ether

실험 절차

A mixture of 37 g of chlorodiphenylmethane and 100 ml of water were refluxed under nitrogen for 16 hours. After cooling the water was decanted and 40 ml of ethanol was added to induce crystallization. The yellow solid was recrystallized 3 times from ethanol to give 21.9 g of dibenzhydryl ether, m.p. 108°-110°.

후처리

  1. temperaturewere refluxed under nitrogen for 16 hours
  2. customwas decanted
  3. addition40 ml of ethanol was added
  4. customcrystallization
  5. customThe yellow solid was recrystallized 3 times from ethanol

출처 및 근거

ORD 기록
ord-de8082e424634f9590c5c2ee70d0ae06
출처 데이터셋
uspto-grants-1984_02
특허 번호
US04431497

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