1-(2-Hydroxyethyl)-2-undecylimidazoline → 1-(2-Hydroxyethyl)-2-(alpha-ethoxycarbonylethyl-undecyl)-2-imidazoline

HRID 1388356

반응식

HRID 1388356 반응식
[OH:1][CH2:2][CH2:3][N:4]1[CH2:8][CH2:7][N:6]=[C:5]1[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[C:20]([O:24][CH2:25][CH3:26])(=[O:23])[CH:21]=[CH2:22]>>[OH:1][CH2:2][CH2:3][N:4]1[CH2:8][CH2:7][N:6]=[C:5]1[CH:9]([CH:21]([C:20]([O:24][CH2:25][CH3:26])=[O:23])[CH3:22])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]

참가 물질

3

반응물 2

HCID 87091-(2-Hydroxyethyl)-2-undecylimidazolineHCID 8821Ethyl Acrylate

생성물 1

HCID 204711381-(2-Hydroxyethyl)-2-(alpha-ethoxycarbonylethyl-undecyl)-2-imidazoline수율 99.7%

실험 절차

Fifty-three and seven tenths g (53.7 g, 0.2 mol) of 1-(2-hydroxyethyl)-2-undecyl-2-imidazoline was melted, and 60 g (0.6 mol) of ethyl acrylate was added. The mixture was reacted at a temperature of 60°-65° C. for 4 hr. in a substantially anhydrous condition. After the reaction, the excess ethyl acrylate was removed by vacuum-topping the reaction mixture at a temperature of 30°-40° C. Seventy-three and a half g (73.5 g) of 1-(2-hydroxyethyl)-2-(α-ethoxycarbonylethyl-undecyl)-2-imidazoline was obtained as a slightly yellow viscous liquid.

후처리

  1. customThe mixture was reacted at a temperature of 60°-65° C. for 4 hr
  2. customAfter the reaction
  3. customthe excess ethyl acrylate was removed by vacuum-topping the reaction mixture at a temperature of 30°-40° C

출처 및 근거

ORD 기록
ord-ff6e6059962f4536b92e5b51718f40ba
출처 데이터셋
uspto-grants-1984_02
특허 번호
US04431672

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