Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-(Trifluoromethylthio)nitrobenzene → 4-((Trifluoromethyl)thio)aniline
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-(Trifluoromethylthio)nitrobenzene | HCID 4210035 | — |
| 촉매 | Adams' catalyst | HCID 345198 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 4-((Trifluoromethyl)thio)aniline | HCID 123054 | — |
반응 단계
To p-nitrophenyl trifluoromethyl sulfide (3.0 g) in absolute ethanol (30 ml) is added Adams catalyst (Pt2O, 0.026 g). The mixture is hydrogenated in a Parr vessel at 50 lbs/sq. in. for about 15 min. The reaction is worked up by filtering through Celite and evaporating to yield p-aminophenyl trifluoromethyl sulfide.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04243819 |
| 출처 데이터셋 | uspto-grants-1981_01 |
| ORD ID | ord-05fcd0edd50c4544a18d607f440a3458 |
| 출처 메모 | uspto-grants-1981_01 |