Benzophenone → Diphenyl Fulvene

HRID 1389721

반응식

HRID 1389721 반응식
[C:1]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:15]1[CH2:19]C=[CH:17][CH:16]=1.[CH2:20](O)C.[O-]CC.[Na+]>>[C:11]1([C:12]2[CH:13]=[CH:14][C:9](=[CH2:20])[C:1]=2[C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH:10]=[CH:17][CH:16]=[CH:15][CH:19]=1

참가 물질

4

반응물 3

HCID 3102BenzophenoneHCID 7612CyclopentadieneHCID 23706232Ethanol sodium ethoxide

생성물 1

HCID 22238549Diphenyl Fulvene

실험 절차

About equal molar amounts of benzophenone and cyclopentadiene are reacted in an ethanol/sodium ethoxide solution according to the method suggested by Kice, JACS 80, 3796 (1958). The dark red crystals obtained are recrystallized from ethanol and dried under vacuum.

후처리

  1. customThe dark red crystals obtained
  2. customare recrystallized from ethanol
  3. customdried under vacuum

출처 및 근거

ORD 기록
ord-b249de72c561426cb9ac8243a264b4dd
출처 데이터셋
uspto-grants-1981_01
특허 번호
US04246167

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