Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Carbonate → N-Formyl-4-bromomethylpiperidine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 4-(Bromomethyl)piperidine hydrobromide | HCID 13503217 | — |
| 용매 | Water | HCID 962 | — |
| 용매 | Methyl formate | HCID 7865 | — |
| 생성물 | N-Formyl-4-bromomethylpiperidine | HCID 19812293 | — |
반응 단계
To a solution of 4-bromomethylpiperidin hydrobromide (12.8 g, 0.05 mole) in water (5 ml), methyl formate (25 ml) and potassium carbonate (10 g) were added and the mixture stirred for 20 hours. The solvent was decanted, and the residue was extracted with two 25 ml portions of ether. The combined organic phases were washed with water, dried and evaporated to give (A) as a colourless oil. The IR spectrum (chloroform) showed a strong band at 1650 cm-1.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04246262 |
| 출처 데이터셋 | uspto-grants-1981_01 |
| ORD ID | ord-54a83d9fc37c4287bd1bcfc5f8fc4ffa |
| 출처 메모 | uspto-grants-1981_01 |