Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Eugenol → Isoeugenol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Eugenol | HCID 3314 | — |
| 촉매 | Osmium chloride (OsCl3) | HCID 83468 | — |
| 생성물 | Isoeugenol | HCID 853433 | 94.5% |
| 생성물 | cis-Isoeugenol | HCID 1549041 | 5.5% |
반응 단계
A mixture of 20 g. of crude clove oil containing about 80% of eugenol and 50 mg. of osmium trichloride is heated for 41/4 hours to 135° C. After distillation, a fraction weighing 13.3 g. and containing, (as determined by gas-liquid chromatography) 5.5% of cis-isoeugenol and 94.5% of trans-isoeugenol is obtained. The yield is 83%, based on the eugenol originally present in the clove oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04138411 |
| 출처 데이터셋 | uspto-grants-1979_02 |
| ORD ID | ord-7cd7cded912840e9a2d1d9103601f19a |
| 출처 메모 | uspto-grants-1979_02 |