Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Mesitylene → (1R*,4S*)-6-allyl-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-ol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Mesitylene | HCID 7947 | — |
| 반응물 | (1R*,4S*)-5-(allyloxy)-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalene | HCID 68584256 | — |
| 생성물 | (1R*,4S*)-6-allyl-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-ol | HCID 68583880 | 80% |
반응 단계
Treatment of (1R*,4S*)-5-(allyloxy)-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalene (15.8 g, 0.069 mol) in refluxing mesitylene generally according to the procedure described for Intermediate 1 gave 12.58 g (80%) of (1R*,4S*)-6-allyl-8-methoxy-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-ol as a colorless oil. Anal. calcd. for C20H22O.0.2H2O: C, 77.02; H, 7.93. Found: C, 76.68; H, 7.88.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07728155B2 |
| 출처 데이터셋 | uspto-grants-2010_06 |
| ORD ID | ord-b13fc06abfcf40eb8c81fec33e28e61c |
| 출처 메모 | uspto-grants-2010_06 |