3,4-Dimethylaniline → 3-[(3,4-Dimethylphenyl)amino)-4,6-dinitrophenol
반응식
[CH3:1][C:2]1[CH:3]=[C:4]([CH:6]=[CH:7][C:8]=1[CH3:9])[NH2:5].[N+:10]([C:13]1[CH:18]=[C:17]([N+:19]([O-:21])=[O:20])[C:16]([OH:22])=[CH:15][C:14]=1F)([O-:12])=[O:11]>C(O)C>[CH3:1][C:2]1[CH:3]=[C:4]([NH:5][C:14]2[CH:15]=[C:16]([OH:22])[C:17]([N+:19]([O-:21])=[O:20])=[CH:18][C:13]=2[N+:10]([O-:12])=[O:11])[CH:6]=[CH:7][C:8]=1[CH3:9]참가 물질
4
반응 조건
- 온도
- 40 °C
실험 절차
6.6 g of 3,4-dimethylaniline was added to a suspension that consists of 4 g of 4,6-dinitro-3-fluorophenol (J. Org. Chem. 1991, 5958) in 100 ml of ethanol, and it was stirred for 7 days at 40° C. After cooling, it was suctioned off, and the residue was recrystallized from ethanol.
후처리
- temperatureAfter cooling
- customthe residue was recrystallized from ethanol
출처 및 근거
- ORD 기록
- ord-b03ae106190c4cf68b5a7dd00b531ee0
- 출처 데이터셋
- uspto-grants-2008_03
- 특허 번호
- US07345075B2
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