Methanol → 1-(Benzyloxy)-4,5-dimethoxy-2-nitrobenzene
반응식
[H][H].[CH3:3][O:4][C:5]1[CH:10]=[C:9]([N+:11]([O-:13])=[O:12])[C:8]([N+]([O-])=O)=[CH:7][C:6]=1[O:17][CH3:18].[CH3:19][OH:20]>O>[CH2:19]([O:20][C:8]1[CH:7]=[C:6]([O:17][CH3:18])[C:5]([O:4][CH3:3])=[CH:10][C:9]=1[N+:11]([O-:13])=[O:12])[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1참가 물질
5
실험 절차
When the formation of hydrogen had ceased (in about 30 min) 456 g (2 mole) of 1,2-dimethoxy-4,5-dinitrobenzene were added and the reaction mixture was refluxed for 2 h. To the solution, 4 l of methanol and 300 ml of water were added. Upon cooling in ice a precipitate was formed which was filtered off and dried. Yield: 369 g (64%); melting point: 141° C.
후처리
- additionwere added
- temperaturethe reaction mixture was refluxed for 2 h
- temperatureUpon cooling in ice a precipitate
- customwas formed which
- filtrationwas filtered off
- customdried
출처 및 근거
- ORD 기록
- ord-b88c9ce2ad294f04a53b8af048137194
- 출처 데이터셋
- uspto-grants-1980_05
- 특허 번호
- US04201584
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