Sodium Methoxide → HCID 178493296, 화합물

HRID 1395554

반응식

HRID 1395554 반응식
[CH:1]([N:4]([CH:18]([CH3:20])[CH3:19])[CH2:5][CH2:6][NH:7][C:8]1[CH:13]=[C:12]([N+]([O-])=O)[CH:11]=[CH:10][N+:9]=1[O-:17])([CH3:3])[CH3:2].[CH3:21][O-:22].[Na+]>CO>[CH:1]([N:4]([CH:18]([CH3:20])[CH3:19])[CH2:5][CH2:6][NH:7][C:8]1[CH:13]=[C:12]([O:22][CH3:21])[CH:11]=[CH:10][N+:9]=1[O-:17])([CH3:3])[CH3:2]

참가 물질

4

반응물 2

HCID 10942334Sodium MethoxideHCID 178457399HCID 178457399, 화합물

생성물 1

HCID 178493296HCID 178493296, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

2-(2-Diisopropylaminoethylamino)-4-nitropyridine-N-oxide (10.0 g., 35.5 mmole) is added to a solution of sodium methoxide (3.0 g., 55 mmole) in dry methanol (100 ml.) and refluxed for 4 hours. The solvent is evaporated and the residue dissolved in chloroform, washed with water, dried over sodium sulfate and evaporated to give oily product.

후처리

  1. temperaturerefluxed for 4 hours
  2. customThe solvent is evaporated
  3. dissolutionthe residue dissolved in chloroform
  4. washwashed with water
  5. dry with materialdried over sodium sulfate
  6. customevaporated
  7. customto give oily product

출처 및 근거

ORD 기록
ord-36d8a0ae002e49b9beada766ba3a8b0e
출처 데이터셋
uspto-grants-1980_05
특허 번호
US04203988

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