2-(2,6-Dinitrophenylamino)ethanol → HCID 23362032, 화합물

HRID 1398934노트

반응식

HRID 1398934 반응식
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-])=O)[C:5]=1[NH:13][CH2:14][CH2:15][OH:16])([O-])=O>[Pd].O1CCCC1>[NH2:1][C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([NH2:10])[C:5]=1[NH:13][CH2:14][CH2:15][OH:16]

참가 물질

4

반응물 1

HCID 233620182-(2,6-Dinitrophenylamino)ethanol

생성물 1

HCID 23362032HCID 23362032, 화합물수율 89%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 8028Tetrahydrofuran용매

실험 절차

Under hydrogen gas atmosphere, a mixture of 2-[(2,6-dinitrophenyl)amino]ethanol (5.54 g, 24.4 mmol) and 10% palladium on carbon (50% wet, 1.1 g) in tetrahydrofuran (240 mL) was stirred at room temperature for 2 h. The reaction mixture was filtered and concentrated in vacuo to give the title compound as a brown oil (3.63 g, 21.7 mmol, 89%).

후처리

  1. filtrationThe reaction mixture was filtered
  2. concentrationconcentrated in vacuo

출처 및 근거

ORD 기록
ord-b048dc9fd0c946ee98d0beb40350427f
출처 데이터셋
uspto-grants-2014_12
특허 번호
US08901141B2

반응 노트

불러오는 중…