Dimethyl malonate → Dimethyl 2-(1-(4-chlorophenyl)-3-(4-ethylphenyl)-3-oxopropyl)malonate

HRID 1402948

반응식

[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]=[CH:9][C:10]([C:12]2[CH:17]=[CH:16][C:15]([CH2:18][CH3:19])=[CH:14][CH:13]=2)=[O:11])=[CH:4][CH:3]=1.[C:20]([O:27][CH3:28])(=[O:26])[CH2:21][C:22]([O:24][CH3:25])=[O:23]>>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([CH:8]([CH:21]([C:20]([O:27][CH3:28])=[O:26])[C:22]([O:24][CH3:25])=[O:23])[CH2:9][C:10]([C:12]2[CH:13]=[CH:14][C:15]([CH2:18][CH3:19])=[CH:16][CH:17]=2)=[O:11])=[CH:6][CH:7]=1

참가 물질

반응물 2

HCID 7943Dimethyl malonate

HCID 41009983-(4-Chlorophenyl)-1-(4-ethylphenyl)prop-2-en-1-one

생성물 1

HCID 66759704Dimethyl 2-(1-(4-chlorophenyl)-3-(4-ethylphenyl)-3-oxopropyl)malonate

실험 절차

By a procedure similar to that of example 1.59.2, starting from 3-(4-chlorophenyl)-1-(4-ethylphenyl)prop-2-en-1-one and dimethyl malonate, dimethyl 2-(1-(4-chlorophenyl)-3-(4-ethylphenyl)-3-oxopropyl)malonate was obtained as pale yellowish solid.

출처 및 근거

ORD 기록: ord-60c116624cf14ab8ae6c3c62600ed348
출처 데이터셋: uspto-grants-2014_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08912186B2

연결된 노트

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